Co2+ (15-crown-5) magnetic supramolecular cation in (Ni(dmit)2)-Pi-spin system

Article Abstract:

Co2+ magnetic cation was incorporated into (Ni(dmit)2)- pi-spin system.

---

Magnetic properties of [Ni(dmit)2]- anions induced by flexible hydrogen-bonded supramolecular cations [(p-xylylenediammonium)0.5(crown

Article Abstract:

Flexible supramolecular cations structures of [(XyDA)0.5-(crown ethers)]+ were incorporated into [Ni(dmit)2]- salts. Hydrogen-bonding interactions between the -CH2-NH3+ moieties of the XyDA cation and the oxygen atoms in the crown ethers yielded sandwich-type supramolecular assemblies.

Analysis, Hydrogen bonding, Hydrogen bonds, Structure

---

Structural phase transition of magnetic [Ni(dmit)(sub 2)](super -) salts induced by supramolecular cation structures of (M(super +))([12])crown-4)(sub 2)

Article Abstract:

Simple supramolecular cation structures of M(super +)([12])crown-4)(sub 2) are introduced into the crystals to seek novel phase transitions in magnetic [Ni(dmit)(sub 2)](super -) salts. The supramolecular cation approach is useful to achieve structural modification of cation sizes and conformations in crystals, which gives a phase transition system coupled with magnetic properties.

Phase transformations (Statistical physics), Phase transitions (Physics), Molecular dynamics, Charge transfer, Atomic properties

Similar abstracts:

• Abstracts: Structural models and thermal desorption energetics for multilayer assemblies of the n-alkanes on Pt(111). Surface-mediated segregation and transport processes in mixed hydrocarbon multilayer assemblies
• Abstracts: Electrochemical Preparation and EPR Studies of LithiumPhthalocyanine. Part 2:Particle-Size-Dependent Line Broadening by Molecular Oxygen and Its Implications as an Oximetry Probe
• Abstracts: Reductive activation of the nitrogen molecule at the surface of 'Electron-Rich' MgO and CaO. The N(sub 2)(super -) surface adsorbed radical ion
• Abstracts: Prediction of ideal permeability of hydrocarbons through an MFI-type zeolite membrane by a combined method using molecular simulation techniques and permeation theory
• Abstracts: Site selective adsorption and templated assembling: Effects on organic-organic heterogeneous interface studied by scanning tunneling microscopy

This website is not affiliated with document authors or copyright owners. This page is provided for informational purposes only. Unintentional errors are possible.